Organocomplejos iónicos de talio (III)

Authors

  • P. Royo
  • R. Serrano

Abstract

The perchlorate group in (Cr,Cl.,)2Tl (CIO4) is readily displaced by several neutral ligands leadíng to the isolation of several cationic organorhallium (III) complexes; j [TI (CcClOjjaLa } (C10«)2 (L = bipy, o-fen), [TI {C^CU),U] CIO. (L = OPPha, OAsPhs) and [TI (CoClj)» (OPPhs)] ClOj have been obtained in this way. The anionic organorhallium (III) complex (EtiN) [TII2 (CaCl5)2] has been prepared by adding EtjNI to a methanolic solution of (CGCIS)! TU. All the compounds have been studied by means of infrared spectroscopy and conductivity measurements.

Published

02-07-2021

Issue

Section

Artículos